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Asymmetric Trinuclear Intermediates in Metal Oxo Cluster Formation: Kinetic Evidence for a Two-Step Esterification

Harry Wilson1, Dietger Van den Eynden1, Ajmal Roshan Unniram Parambil1

  • 1Department of Chemistry, University of Basel, Mattenstrasse 24a, 4058 Basel, Switzerland.

ACS Nano
|February 12, 2026
PubMed
Summary

Researchers elucidated the nonaqueous formation mechanism of metal oxo clusters, revealing a key esterification step essential for synthesizing these valuable building blocks for metal-organic frameworks and 3D-printing.

Keywords:
EXAFSesterificationkineticsmechanismmetal oxo clusterpair distribution function

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