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Detecting supramolecular organic nanoparticles during heat wave.

Renyi Zhang1,2,3,4, Yixin Li1, Jiayun Zhao2

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New particle formation, a key source of fine aerosols, unexpectedly occurred during a heat wave. Scientists discovered organic acids self-assemble into nanoparticles, explaining high-temperature formation and its broad atmospheric relevance.

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Area of Science:

  • Atmospheric Chemistry
  • Environmental Science
  • Nanoparticle Science

Background:

  • New particle formation (NPF) is a primary source of tropospheric fine aerosols.
  • NPF is commonly believed to be thermodynamically limited by species volatility, making it unfavorable at high temperatures.

Purpose of the Study:

  • To investigate the mechanisms behind frequent new particle formation (NPF) observed during a heat wave.
  • To determine the chemical composition of newly formed nanoparticles at high temperatures.

Main Methods:

  • Conducted an intensive field campaign during a heat wave.
  • Performed size-resolved chemical composition measurements of nanoparticles down to 3 nanometers.

Main Results:

  • Observed frequent NPF events during the heat wave, contrary to common assumptions.
  • Identified carboxylic acids as the dominant species in newly formed nanoparticles.
  • Uncovered a spontaneous self-assembly mechanism for organic acids to form supramolecular nanoparticles.

Conclusions:

  • The self-assembly of organic acids provides a mechanism for NPF at high temperatures.
  • This finding explains the unexpected occurrence of NPF during heat waves and its prevalence in various atmospheric conditions.
  • Results have implications for understanding aerosol impacts on climate, cloud formation, and public health, especially in the context of global warming.