Eco-Friendly Illite as a Sustainable Solid Lubricant in Calcium Grease: Evaluating Its Thermal Stability,...

This study investigates the influence of the additive illite on the thermal, tribological, and energy efficiency characteristics of calcium grease (CG) at different concentrations (0.05 wt.%, 0.1 wt.%, 0.2 wt.%, 0.4 wt.%, 0.6 wt.%, and 0.8 wt.%). Thermo-gravimetric analysis under inert and oxidative atmospheres revealed that illite enhances thermal stability by increasing inorganic residue under N₂, but promotes oxidative degradation under O₂, limiting practical thermal use to around 400 °C. Grease with 0.1 wt.% illite (CGI2) performed well in tribological tests by reducing the coefficient of friction and wear scar diameter by 53% and 57%, respectively, compared to the base grease. Fleischer's energy-based wear model showed that all grease samples operated within the mixed friction regime, and CGI2 exhibited a 93% higher apparent frictional energy density and a substantially lower wear intensity that was 47% lower than the base grease, indicating improved energy dissipation and wear resistance. All samples had the same weld load (1568 N), but CGI2 had a 21% higher load-wear index than the base grease in the extreme-pressure test, indicating better load-carrying capacity. In the energy consumption test, a 6% reduction in current consumption was observed in CGI2 in comparison with the base grease. Overall, illite at an optimal concentration significantly enhances lubrication performance, wear protection, and energy efficiency.