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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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In precipitation gravimetry, the precipitating agent should react specifically or selectively with the analyte. While a specific reagent reacts with the analyte alone, a selective reagent can react with a limited number of chemical species.
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The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
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Localized Particle Segregation Induced by Leidenfrost Droplet Motion across Superheated Powder Bed.

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Leidenfrost droplets can locally segregate particles in powder beds for additive manufacturing. This method enables site-specific properties in metallic parts by controlling particle size distribution.

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Area of Science:

  • Materials Science
  • Additive Manufacturing
  • Fluid Dynamics

Background:

  • Mechanical properties of additively manufactured metallic parts depend on powder bed particle size distribution.
  • Localized modification of particle size distribution is needed for heterogeneous metallic parts with site-specific properties.
  • Current methods for localized particle segregation are limited.

Purpose of the Study:

  • To demonstrate a simple method for localized particle segregation in powder beds using Leidenfrost droplets.
  • To investigate the parameters influencing particle segregation and deposition patterns.

Main Methods:

  • Utilizing Leidenfrost droplets traveling at a constant speed to fluidize and segregate powder particles.
  • Analyzing the effect of powder bed thickness, droplet velocity, and fluid type (water vs. ethanol) on particle segregation.
  • Quantifying the deposition of larger particles based on varying initial particle proportions.

Main Results:

  • Leidenfrost droplets effectively segregate particles, with larger particles preferentially deposited in the droplet's wake.
  • Increased powder bed thickness and slower droplet velocity enhance the deposition of larger particles.
  • Changing the fluid to ethanol reduced fluidization velocity, promoting further segregation, especially at lower powder bed thicknesses.

Conclusions:

  • Leidenfrost droplets offer a promising technique for localized particle segregation in powder beds.
  • This method allows for the fabrication of heterogeneous metallic parts with tailored, site-specific properties.
  • The study highlights the potential for advanced additive manufacturing through controlled particle size distribution.