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Related Concept Videos

Conformations of Ethane and Propane02:18

Conformations of Ethane and Propane

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In an organic molecule, free rotation about the carbon-carbon single bond results in energetically different conformers of the molecule. Due to this rotation, called the internal rotation, ethane has two major conformations — staggered and eclipsed.
Staggered conformation is a low energy and more stable conformation with the C-H bonds on the front carbon placed at 60°dihedral angles relative to the C-H bonds on the back carbon, leading to a reduced torsional strain. In staggered...
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Conformations of Butane02:20

Conformations of Butane

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Unlike ethane and propane that have only two major conformations, butane has more than two conformers. The staggered form of butane in which the bulky methyl groups on the two carbons are placed on opposite sides, that is, at a dihedral angle of 180°, is the lowest energy, most stable form — called the anti conformer. This conformation is stabilized due to the absence of steric repulsion between the largely spaced out methyl groups. The other two staggered conformations are...
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π Molecular Orbitals of 1,3-Butadiene

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Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
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Stability of Conjugated Dienes01:28

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Introduction
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The synthesis of phenol from benzene via cumene and cumene hydroperoxide is called the Hock process. First, a Friedel–Crafts alkylation reaction of benzene with propene gives cumene. Then cumene forms cumene hydroperoxide via a radical chain reaction. In the chain initiation step, the benzylic hydrogen is abstracted to give a benzylic radical. In the chain propagation step, the benzylic radical reacts with an oxygen diradical to form a cumene hydroperoxide radical. The cumene...
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The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
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Updated: May 5, 2026

In-situ Tapering of Chalcogenide Fiber for Mid-infrared Supercontinuum Generation
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Supercontinuum generation in 1-decanol.

Nathan G Drouillard, Jacob A Stephen, Chathurangani Jayalath Arachchige

    Optics Express
    |February 20, 2026
    PubMed
    Summary
    This summary is machine-generated.

    1-decanol liquid offers a stable, less toxic alternative for ultrafast nonlinear optics experiments. It generates a broad supercontinuum spectrum, comparable to CS2, with significant nonlinear properties.

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    Area of Science:

    • Nonlinear Optics
    • Ultrafast Spectroscopy

    Background:

    • Solids are used for spectral broadening in ultrafast experiments due to high nonlinearity but suffer from damage sensitivity.
    • Liquids present an alternative nonlinear medium with comparable nonlinearity and better resistance to permanent damage.

    Purpose of the Study:

    • To investigate 1-decanol as a stable, less toxic liquid nonlinear medium for ultrafast experiments.
    • To characterize the supercontinuum generation and nonlinear optical properties of 1-decanol.

    Main Methods:

    • Generation of a supercontinuum spectrum in 1-decanol.
    • Measurement of the nonlinear index of refraction, including the n4 contribution.

    Main Results:

    • A supercontinuum spanning approximately 450 nm to 950 nm was generated in 1-decanol.
    • 1-decanol exhibits a significant n4 contribution, resulting in nonlinearity comparable to CS2.
    • The generated supercontinuum spectrum remained stable for at least 30 minutes.

    Conclusions:

    • 1-decanol is a promising liquid nonlinear medium for ultrafast applications.
    • Its comparable nonlinearity to CS2, coupled with lower volatility and toxicity, makes it advantageous.
    • The observed spectral stability supports its use in long-term experiments.