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Updated: Feb 26, 2026

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
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Reversible Transformation Mechanism between Pd4 and Pd10 Clusters and Their Catalytic Hydrogenation Activities.

Lei Li1, Xiongkai Tang1, Yani Gu1

  • 1New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

ACS Nano
|February 25, 2026
PubMed
Summary

This study reveals how palladium nanoclusters transform structurally, driven by Pd2(0) and hydrogen bonds. These transformations impact their catalytic activity in olefin hydrogenation, with Pd10 clusters showing high regioselectivity.

Keywords:
catalytic mechanismnanoclusterolefin hydrogenationpalladiumregioselectivitystructural transformation

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