Microstructure-regulated V₂O₃ cathodes for high-rate and durable aqueous zinc-ion batteries

Vanadium(III) oxide (V₂O₃) has emerged as a promising cathode material for aqueous zinc-ion batteries owing to its high theoretical capacity based on reversible two-electron redox chemistry. However, the cycling stability and reaction kinetics are highly sensitive to its microstructural characteristics, which remain insufficiently understood. Here, we report a facile and scalable synthesis of V₂O₃via combining an oil-bath reaction and a controlled calcination process, enabling precise regulation of particle morphology and microstructure through calcination time. Systematic microstructural evolution is correlated with zinc-ion storage behavior, revealing that optimized architectures effectively promote ion transport kinetics and structural stability. Coupled with a high-concentration water-in-salt electrolyte to suppress parasitic reactions, the optimized V₂O₃ cathode delivers a high specific capacity of 453.8 mAh g^-1 at 0.05 A g^-1, exceptional rate capability with 180 mAh g^-1 retained at 10 A g^-1, and prolonged cycling stability of 210 mAh g^-1 after 1000 cycles at 1 A g^-1. This work elucidates the underlying structure-property relationship governed by the microstructure and also provides valuable insights into the design of high-performance cathode materials for advanced energy storage systems.