Material Composition Design for Long-Term Stability of Solid Oxide Fuel Cell Based on Creep Damage and Failure...

Electrode degradation represents a primary factor contributing to the performance decay. The composition design of electrode materials directly determines the long-term stability of solid oxide fuel cell (SOFC) under high-temperature service conditions. This paper focuses on the effect of anode and cathode material compositions on the creep damage and failure probability of SOFCs after 50,000 h creep. The results reveal an optimal Ni content range for mechanical integrity. Specifically, increasing the Ni volume fraction from 30% to 50% results in a reduction in the creep damage. In contrast, extending the increase to 60-70% causes a general reversal of this trend, with the creep damage showing an overall increase. The paper concludes that the Ni volume fraction of 50-60% is appropriate to maintain the long-term operation of SOFC. The La_0.8Sr_0.2MnO₃ (LSM) volume fraction with higher electrochemical efficiency can be selected for cathode manufacturing. This study provides a reference for developing long-life SOFC electrode materials.