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Fluorescence Analysis of Local Microenvironments in Polymer Films Using Solvatochromic Dyes.

Tomoharu Matsushita1, Takuya Tanaka1, Yuki Sawatari1

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Summary

Solvatochromic dyes reveal local polymer microenvironments and their impact on fluorescence. This study shows dyes can monitor polymer states and enable fluorescence-based temperature sensing.

Keywords:
fluorescence lifetime (TCSPC)intramolecular charge transfer (ICT)local polaritymicroheterogeneitypolymer filmspolymer microenvironmentratiometric fluorescence thermometrysolvatochromic dyestructural relaxation

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Area of Science:

  • Materials Science
  • Photophysics
  • Polymer Chemistry

Background:

  • Functional polymer films' photophysical behavior is complex, not solely explained by bulk properties.
  • Understanding local polymer microenvironments is crucial for advanced material applications.

Purpose of the Study:

  • Investigate how local polymer microenvironments influence fluorescence responses using molecular probes.
  • Evaluate the potential of solvatochromic dyes for polymer-state monitoring and temperature sensing.

Main Methods:

  • Employed two solvatochromic dyes (FπPCM and PK) as molecular probes in various polymer matrices.
  • Prepared polymer films via solution casting and examined photophysical properties (wavelength, quantum yield, lifetime).
  • Utilized fluorescence lifetime analysis and temperature-dependent measurements on polymer blend films.

Main Results:

  • Dye fluorescence varied significantly across different polymer matrices, influenced by polarity, chain packing, and dye-polymer interactions.
  • Microscopic heterogeneity was detected in miscible polymer blend films.
  • Reproducible temperature sensing was achieved using ratiometric fluorescence analysis in specific blend films.

Conclusions:

  • Solvatochromic dyes are effective optical probes for characterizing local polymer microenvironments.
  • These dyes offer potential for real-time polymer-state monitoring and advanced fluorescence-based temperature-sensing applications.