Radiation-entropy generation by leaf and negentropy build-up of plant as dissipative structure

Photosynthesis is a simple reaction for any plant, but it has not been achieved artificially due to the difficulty in radiation entropy production by processing PAR (photosynthetically active radiation). In this study, a plant is shown to be a self-organising dissipative structure; since, it's leaf generates radiation entropy for the existence of plant with possible growth. Entropy-energy ratio (s_E) of PAR released after processing (s_E,rel) much exceeds s_E of light absorbed, s_E,in (< < s_E,rel). Plant builds its negentropy $\left(s_{\text{neg},\text{rad}}\right)$ by the difference, $s_{\text{E,rel}}-s_{\text{E,in}}$ , but only a part of this difference can be the source of free energy as plant-growth. The remaining part of $\left(s_{\text{neg},\text{rad}}\right)$ is dissipated as the excess payment of negentropy debt, towards mandatory 2nd Law compliance. Change from low s_E,in to high s_E,rel by the plant-leaf is amplified by a huge factor, c², while determining $\left(s_{\text{neg},\text{rad}}\right)$ ; where, c is the speed of light. Therefore, even a small increase in s_E,rel and small reduction in s_E,in can significantly increase $\left(s_{\text{neg},\text{rad}}\right)$ . Thermodynamic performance of photosynthesis depends on the processing level of PAR, ${\Pi }_{\text{E},\text{leaf}}=\left(s_{\text{E},\text{rel}}\left(\phantom{s_{\text{E},\text{rel}}{s}_{\text{E},\text{in}}}\right)s_{\text{E},\text{in}}\right)$ , $\left(s_{\text{neg},\text{rad}}\right)$ , and is limited by the maximum photosynthetic efficiency in PAR, ${\eta }_{\text{ph},\text{PAR}\_\text{max}}$ (it increases with ${\Pi }_{\text{E},\text{leaf}}$ ).