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Composite Adsorbent "1-Ethyl-3-methylimidazolium Acetate [EMIM] [Ac] into Mesoporous Silica Gel" for Adsorption Heat
Angelo Freni1, Elisa Passaglia1, Emilia Bramanti1
1Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale Delle Ricerche, Via G. Moruzzi 1, 56124 Pisa, Italy.
Abstract:
The aim of this work is to prepare and characterize a composite adsorbent comprising the hydrophilic ionic liquid 1-ethyl-3-methylimidazolium acetate [EMIM-Ac] composite supported on mesoporous silica gel for application in adsorption heat storage systems. Water adsorption/desorption isotherms were measured gravimetrically at T = 40, 50, 70 °C across a relative humidity (RH) range of 0-0.8, demonstrating a high adsorption capacity (up to 0.71 g/g at 50 °C and RH = 0.8, for a 50 wt % [EMIM-Ac] loading). Full process reversibility and negligible ad/desorption hysteresis were also verified. Thermal stability of the prepared silica/[EMIM-Ac] composites was confirmed up to approximately T = 200 °C. Structural stability of samples subjected to repeated ad/desorption aging cycles was verified via FT-IR, High-Resolution Solid-State NMR, and Time-Domain NMR spectroscopy. Finally, the thermodynamic analysis based on adsorption experimental data indicated that the silica/[EMIM-Ac] composite is highly suitable for adsorption heat storage, providing a volumetric density of 600-920 MJ/m3 at regeneration temperatures below 100 °C.
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