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Related Concept Videos

IR Frequency Region: Fingerprint Region01:03

IR Frequency Region: Fingerprint Region

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IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 cm−1. The absorptions resulting from single-bond vibrations of the N–H, C–H, and O–H stretch at higher wavenumbers and appear on the left side of the spectrum. The stretching absorptions of the C≡C and C≡N occur between 2100–2300 cm−1. In contrast, those arising from stretching absorptions of the...
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Target-enhanced double-pulse LIBS coupled with feature-fused CNN for mechanistic and interpretable coffee origin

Xiaoyong He1, Kaiqiang Que1,2, Tingrui Liang1

  • 1School of Telecommunications Engineering & Intelligentization, Dongguan University of Technology, Dongguan 523808, China.

Food Chemistry: X
|March 23, 2026
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Summary

This study introduces a new method combining Potassium-assisted Double-Pulse Laser-Induced Breakdown Spectroscopy (DP-LIBS) with a Feature-Fused Convolutional Neural Network (CNN) for accurate coffee origin authentication. The novel approach achieves 99% accuracy in identifying coffee provenance, outperforming traditional methods.

Keywords:
1D Grad-CAM++Coffee origin authenticationDouble-pulse LIBSFeature-fused CNNSHAPTrace element analysis

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Area of Science:

  • Analytical Chemistry
  • Food Science
  • Spectroscopy

Background:

  • Authenticating coffee's geographical origin is crucial to prevent economically motivated adulteration.
  • Rapid trace-element analysis in complex organic matrices like coffee is challenging.
  • Existing methods often struggle with accuracy and speed in complex samples.

Purpose of the Study:

  • To develop a novel synergistic framework for precise coffee traceability.
  • To integrate Potassium-assisted Double-Pulse Laser-Induced Breakdown Spectroscopy (DP-LIBS) with a Feature-Fused Convolutional Neural Network (CNN).
  • To enable autonomous extraction of spatial-spectral patterns for enhanced authentication.

Main Methods:

  • Utilized Potassium-assisted orthogonal Double-Pulse Laser-Induced Breakdown Spectroscopy (DP-LIBS) with a KHCO₃ solid target for enhanced signal sensitivity.
  • Developed a Feature-Fused CNN architecture by concatenating normalized spectral data with statistical descriptors.
  • Implemented a dual-interpretability strategy using SHAP analysis and 1D Grad-CAM++ for decision logic elucidation.

Main Results:

  • Achieved a superior classification accuracy and F1-score of 99.00% for coffee traceability.
  • Outperformed traditional algorithms like XGBoost (95.75%), PLS-DA (92.50%), RF (86.50%), and KNN (75.75%).
  • Demonstrated robustness with high precision (>94%) even under severe noise interference (30 dB SNR).

Conclusions:

  • The Feature-Fused CNN model effectively recognizes synergistic covariance of trace elements (Fe, Cr, Cu, K) for superior coffee provenance verification.
  • The integrated DP-LIBS and CNN framework offers a robust and mechanically interpretable strategy for food authentication.
  • This approach significantly advances the capability for rapid and precise trace-element analysis in complex organic matrices.