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Related Concept Videos

Determination of Crystal Structures01:29

Determination of Crystal Structures

58
In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
58

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Related Experiment Video

Updated: Mar 24, 2026

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Shallow-Trap Perovskite Scintillators for High-Resolution, Ghosting-Free X-Ray Imaging.

Weihong Li1, Yao Yao1, Libin Zheng1

  • 1State Key Laboratory of Green and Efficient Development of Phosphorus Resources, New Cornerstone Science Laboratory, College of Chemistry, Fuzhou University, Fuzhou, China.

Angewandte Chemie (International Ed. in English)
|March 23, 2026
PubMed
Summary

New perovskite scintillators offer long-lasting X-ray imaging at room temperature by utilizing shallow traps. This breakthrough overcomes ghosting and improves recyclability for advanced flexible X-ray detectors.

Keywords:
Electronic trapsGhosting‐free X‐ray imagingPerovskite scintillatorRadioluminescence afterglowX‐ray detector

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Area of Science:

  • Materials Science
  • Solid-State Physics
  • Radiochemistry

Background:

  • Solution-processed scintillators promise flexible, high-resolution X-ray imaging.
  • Deep electronic traps in current scintillators cause ghosting and limit recyclability due to high-temperature readout requirements.

Purpose of the Study:

  • To develop perovskite scintillators with shallow traps for persistent radioluminescence at room temperature.
  • To enable ghosting-free, recyclable, and high-resolution X-ray imaging applications.

Main Methods:

  • Synthesized Cs2ZrCl6:Te4+ perovskite microcrystals.
  • Investigated X-ray-induced defect formation using spectroscopic and theoretical studies.
  • Fabricated flexible scintillating films by embedding microcrystals in a PDMS matrix.

Main Results:

  • Discovered X-ray-induced Frenkel defect-associated shallow traps in Cs2ZrCl6:Te4+.
  • Achieved long-lasting radioluminescence at room temperature due to efficient charge trapping and thermal release.
  • Demonstrated ghosting-free, time-lapse X-ray imaging with 18.5 lp mm-1 spatial resolution and recyclability.

Conclusions:

  • Shallow-trap perovskite scintillators overcome limitations of traditional deep-trap materials.
  • Optimized defect landscape via Te4+ doping enhances charge dynamics for persistent luminescence.
  • Developed flexible X-ray imaging technology with potential for next-generation applications.