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ipso-Halogenation of Arylsilanes Using a Carborane Sulfide Catalyst

Masanobu Ogikubo1, Koji Hirano1,2, Yuji Nishii1,2,3

  • 1Department of Applied Chemistry, Graduate School of Engineering, The University of Osaka, Suita, Osaka 565-0871, Japan.

Organic Letters
|March 23, 2026
PubMed
Summary

This study introduces a new method for ipso-halogenation of arylsilanes using a Carborane-SMe catalyst. This approach enables access to challenging substitution patterns with excellent functional group tolerance.

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