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Published on: September 12, 2014
Deep red photocatalysis via direct S0 → T1 excitation of an Ir(iii) complex using 740 nm light
Robert J Ortiz1, Dion B Nemez1, Mahtasim Bhuiyan1
1Department of Chemistry and the Manitoba Institute for Materials, University of Manitoba 144 Dysart Road Winnipeg MB R3T 2N2 Canada david.herbert@umanitoba.ca.
Abstract:
We report the first examples of deep-red Ir(iii) photochemistry using [Ir(ppy)2(p-biphe)]PF6 (ppy = 2-phenylpyridine; p-biphe = 6,6',7,7'-biphenanthridine). Red light (740 nm) directly excites into the triplet manifold, populating a long-lived excited state (54 ± 3 ns) with mixed triplet metal-to-ligand charge-transfer/ligand-centered character capable of energy-transfer and electron-transfer photocatalysis.
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