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Quantifying Photochemical Propulsion in Light-Powered Janus Micromotors.

Katherinne I Requejo1,2,3, Cristhian Cañari-Chumpitaz2,3,4, Vida Jamali2,5

  • 1California Institute for Quantitative Biosciences, University of California, Berkeley, Berkeley, California 94720, United States.

ACS Nano
|May 5, 2026
PubMed
Summary
This summary is machine-generated.

Light-activated Janus particles convert light into motion, offering insights into microscale engines. Researchers quantified propulsion dynamics and forces, establishing a framework for designing light-powered micromotors.

Keywords:
Janus micromotorsactive colloidsforcelight-activated Janus particlesoptical tweezersself-propulsion

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Nanotechnology

Background:

  • Active colloids convert light into motion, serving as models for nonequilibrium systems and microscale engines.
  • Understanding light-activated Janus particles is crucial for developing advanced micro-propulsion systems.

Purpose of the Study:

  • To quantify the propulsion dynamics and force generation of light-activated gold-titanium dioxide (Au-TiO2) Janus particles.
  • To investigate the influence of particle size, metal thickness, fuel concentration, and illumination wavelength on propulsion.
  • To establish a single-particle framework for quantifying active forces in photocatalytic Janus particles.

Main Methods:

  • Characterization of light-activated Au-TiO2 Janus particles and Au-PS@TiO2 analogues using varying parameters.
  • Measurement of propulsion velocities under different conditions.
  • Optical tweezers to measure transient propulsion forces on single particles.
  • Simulations to validate the role of transient forces in active motion.
  • Functionalization with DNA polymers to assess effects on directional motion.

Main Results:

  • Average velocities of 33.2 ± 2.99 μm s⁻¹, with instantaneous velocities up to ~100 μm s⁻¹.
  • Transient propulsion forces with a median of 4.5-6.2 pN, lasting 21-41 ms and reaching up to 20 pN.
  • Simulations confirmed the role of these forces in observed trajectories.
  • DNA functionalization enhanced directional motion by reducing rotational diffusion.

Conclusions:

  • Photochemical energy conversion at the Au-TiO2 interface governs particle propulsion.
  • A single-particle framework for quantifying active forces in photocatalytic Janus particles has been established.
  • Design principles for light-powered micromotors have been identified, paving the way for future applications.