Modifying wood with a carboxymethyl-activated delignification/borate composite modifier to achieve high efficiency...

Solar interfacial evaporation holds strong potential for sustainable desalination. Balancing high evaporation rates with long-term salt-fouling resistance remains a major challenge. A carboxymethylated delignified wood (BDCMW) aerogel is fabricated from natural balsa through sequential delignification, carboxymethylation, and borax cross-linking. This process preserves the vertically aligned porous channels while introducing abundant hydrophilic functional groups. The resulting structure provides strong water transport capability and reduces evaporation enthalpy by promoting the formation of intermediate water with weakened hydrogen bonds. Polypyrrole (PPy) is then polymerized in situ on the BDCMW scaffold to produce the BDCMW@PPy composite evaporator. The BDCMW@PPy evaporator achieves an evaporation rate of 4.68 ± 0.08 kg·m^-2·h^-1 under 1-sun illumination, with an evaporation efficiency of 85 ± 2%. In addition, the evaporator shows strong antibacterial activity and resistance to salt fouling. This work presents a scalable strategy for developing sustainable, highly efficient, and salt-fouling-resistant solar interfacial evaporators.