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Updated: May 8, 2026

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Local Thermal Strain Regulated Solid Electrolyte Interphase with Advanced High-Temperature Tolerance.

Gaobo Chang1, Hanqing Zhao1, Boyan Cui1

  • 1State Key Laboratory of Clean and Efficient Coal Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, P. R. China.

Journal of the American Chemical Society
|May 6, 2026
PubMed
Summary
This summary is machine-generated.

Negative thermal expansion oxide ZrW2O8 stabilizes the solid electrolyte interphase (SEI) on hard carbon anodes. This improves sodium-ion battery performance and durability, especially at high temperatures.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid electrolyte interphase (SEI) instability on hard carbon (HC) anodes hinders sodium-ion battery (SIB) application, particularly under high-temperature cycling.
  • Developing robust SEI layers is crucial for enhancing SIB performance and cycle life.

Purpose of the Study:

  • To introduce negative thermal expansion (NTE) oxide ZrW2O8 to catalyze SEI formation and improve its structural durability.
  • To investigate the effect of NTE ZrW2O8 on interfacial Na+ transfer and initial Coulombic efficiency (ICE) in SIBs at elevated temperatures.

Main Methods:

  • Incorporation of NTE ZrW2O8 into HC anodes.
  • Electrochemical testing of HC anodes and full SIB cells at various temperatures (0-80 °C).
  • Analysis of SEI properties, including thermal strain mitigation and mechanical stability.

Main Results:

  • NTE ZrW2O8 effectively catalyzed SEI formation, significantly enhancing interfacial Na+ transfer and ICE.
  • The optimized HC anode exhibited 93.3% ICE and sustained over 8000 cycles at 5.0 A g-1.
  • Remarkable capacity retentions were achieved at high temperatures: 86.3% at 60 °C and 63.4% at 80 °C.
  • Full battery capacity retention at 60 °C improved from 22.8% to 64.0%.

Conclusions:

  • NTE ZrW2O8 imparts self-relieving functionality and mechanical elasticity to the SEI, improving temperature tolerance and stability.
  • This novel thermal strain modulation strategy shows great promise for designing stable SIBs under extreme conditions.