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Factors maximising photoinduced electron-transfer-coupled phase migration to boost biphasic photocatalysis
Ren Itagaki1, Akinobu Nakada1,2, Hajime Suzuki1,3
1Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan. nakada@tmu.ac.jp.
None:
The use of biphasic solutions has recently attracted attention as an effective strategy to spatially extend photoinduced charge separation between the photocatalyst and electron donors/acceptors via phase migration, enabling efficient photocatalysis. Herein, key parameters of biphasic photocatalytic systems, namely, diffusion in solution, liquid-liquid phase boundary, and phase transfer equilibrium, were modulated in detail, unveiling design principles that maximise the benefits of biphasic systems.
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