Evaluating the impact of CO2 on the geomechanical and geochemical properties of different rock types
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Updated: May 14, 2026

A Uniaxial Compression Experiment with CO2-Bearing Coal Using a Visualized and Constant-Volume Gas-Solid Coupling Test System
Published on: June 12, 2019
William Holdbrook Dontoh1, Mubarak M Alhajeri2, Kim Mews1
1Tertiary Oil Recovery Program (TORP), University of Kansas, Department of Chemical & Petroleum Eng Lawrence Kansas USA rbarati@gmail.com.
Abstract:
The interaction between CO2 and water in subsurface environments plays a critical role in altering the geomechanical properties of rocks, with significant implications for carbon sequestration, reservoir integrity, and underground storage applications. This study evaluates the impact of CO2-water exposure on the strength, elasticity, porosity, and mineralogical composition of different rock types, including sandstone, limestone, dolomite, basalt and shale. Laboratory experiments were conducted to characterize the initial petrophysical and geomechanical properties of the rock samples before subjecting them to CO2-saturated water under controlled pressure and temperature conditions. Post-exposure analyses were performed using nanoindentation SEM-EDS and X-ray diffraction (XRD) to assess mineralogical and structural changes. The results indicate that CO2-water interaction leads to varying degrees of mechanical weakening, with carbonate rocks showing significant dissolution effects and reduced elastic modulus. In contrast, silicate-rich rocks like sandstone exhibited comparatively lower degradation due to their mineralogical stability. These findings highlight the importance of rock-specific evaluations in subsurface engineering applications, particularly in optimizing CO2 storage strategies and ensuring long-term stability. Further studies incorporating extended exposure durations and field-scale validation are recommended to enhance predictive models for rock behavior in CO2-rich environments.
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