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Related Concept Videos

The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Ionic Association01:28

Ionic Association

The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.

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Updated: May 19, 2026

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Published on: December 20, 2016

Constructing Superionic Heterointerface via Multiphase Engineering to Achieve Stable Oxyhalide-Based All-Solid-State

Xinglong Jiang1, Zecheng Fang1, Tao Liu1

  • 1Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing, People's Republic of China.

Angewandte Chemie (International Ed. in English)
|May 18, 2026
PubMed
Summary
This summary is machine-generated.

Amorphous oxyhalides show promise for solid-state batteries but suffer from low ionic conductivity. Incorporating ZrB2 and ZrN into an amorphous lithium oxyhalide matrix enhances Li+ transport and interfacial stability, boosting battery performance.

Keywords:
all‐solid‐state batteriesamorphizationhalide solid electrolytesoxyhalidessuperionic heterointerface

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Chemistry

Background:

  • Amorphous oxyhalides are attractive solid-state electrolytes (SSEs) for all-solid-state batteries (ASSBs) due to their stability and deformability.
  • However, their practical application is limited by low room-temperature ionic conductivity and interfacial reactions with cathodes.

Purpose of the Study:

  • To enhance Li+ transport and interfacial stability in amorphous lithium oxyhalides for ASSBs.
  • To investigate the effect of incorporating ZrB2 and ZrN on the properties of amorphous Li2O-ZrCl4 (LZCO) matrix.

Main Methods:

  • A facile multiphase regulation strategy was employed by incorporating ZrB2 and ZrN into an amorphous 1.3Li2O-ZrCl4 (LZCO) matrix.
  • The resulting composite material (LZCOBN0.1) was characterized for its ionic conductivity and electrochemical performance in ASSBs.

Main Results:

  • The incorporation of ZrB2 and ZrN created superionic heterointerfaces and a more continuous Li+ conduction network, increasing ionic conductivity to 2.41 mS cm-1.
  • ASSBs utilizing LZCOBN0.1 exhibited a high initial capacity (210 mAh g-1) and excellent cycling stability, retaining 82.7% capacity after 2000 cycles.
  • The multiphase architecture mitigated interfacial side reactions and improved interface compatibility.

Conclusions:

  • Phase engineering via multiphase regulation is a viable strategy for developing high-performance amorphous oxyhalide-based SSEs.
  • The developed LZCOBN0.1 composite demonstrates significant potential for practical ASSB applications.