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Reactive Vapor Deposition of Conjugated Polymer Films on Arbitrary Substrates
Published on: January 17, 2018
Monomer-level strategy for high refractive index without visible-light absorption: vinylthiophene incorporation into
Kanon Hirota1, Yuta Takemasa1, Tomoki Nakagawa1
1Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1, Komaba, Meguro-ku, Tokyo, 153-8902, Japan. ctakemasa@g.ecc.u-tokyo.ac.jp.
Abstract:
We present a monomer-level design strategy for high-refractive-index polymers that overcomes the trade-off between refractive index and visible-light transparency. Densely incorporating highly polarizable vinylthiophene units around group 14 element centers results in refractive indices up to 1.69, maintains minimal visible-light absorption, and enables their application as index-enhancing additives for polymers.

