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Updated: May 28, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Labilized ligands under ultra-confinement: a solid-state 2H NMR investigation of Ln(BH4)2(THF)2/HY30
Scott A Southern1, Yuting Li1, Takeshi Kobayashi1
1Chemical and Biological Sciences Division, Ames National Laboratory, Ames, IA 50011, USA. fperras@ameslab.gov.
Abstract:
Variable-temperature 2H NMR reveals that the THF ligands are highly labile in Ln(BH4)2(THF)2/HY30, undergoing exchange between Ln sites under confinement via low-coordinate intermediates. Potency in catalytic C-H borylation likely emerges from access to highly electrophilic, electronically unsaturated species.
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