Effects of Preheating on Internal Modification and Welding Strength of Glass by Ultrafast Laser Pulses

Glass preheating prior to laser scanning is expected to enhance internal modification morphology; however, its effect on weld seam topology and welding strength have not been investigated. In the current work, the effects of preheating on ultrafast laser (184 fs and 10 ps) internal modification and welding strength of borosilicate glass slides are investigated. For the internal modification experiments, pulse energy of 30-100 µJ and repetition rate of 10 kHz are used by focusing a laser beam at the interface of optically contacted slides at room temperature (RT ≈ 23 °C), 150 and 200 °C. Welding is conducted by a pulse energy of 4.5-18 µJ and repetition rate of 200 kHz using pre-clamped glass slides with a scanning speed of 10 mm/s at RT and 150 °C. Also, for welding, the optimum number of scans and hatching spacing are identified. Filamentation experiments show that discoloration is not significant when preheat temperature reaches 200 °C. Compared to 10 ps, pulse duration of 184 fs can produce a 19% narrower plasma-modified region at both RT and 150 °C and a 13% wider heat-affected zone at 150 °C. Welding using optimum conditions of 5 scans and 200 µm hatch, and "crack-free" laser parameters produces an average strength of: 50 ± 3.2 MPa at RT and 40 ± 2 MPa at 150 °C for 184 fs compared to 35 MPa at RT and 32 MPa at 150 °C for 10 ps, using 10 replicates each. However, the welding strength upon preheating to 150 °C using 184 fs is still 25% higher compared to average reported laser welding bonding strength, while the 10 ps strength is within the reported average. The enhanced welding strength for 184 fs can be attributed to reduced microcracking, especially when "crack free" combinations are utilized.