Terahertz Properties of GeAsSeSbSnTe Chalcogenide Glassy Semiconductors

Chalcogenide glasses are known as optical materials for the infrared spectral range. These compounds may also be of interest as materials for the low-frequency part of the terahertz range of electromagnetic waves, which is currently being intensively studied in connection with the numerous possible applications of terahertz radiation. However, the terahertz optical characteristics of chalcogenide glasses remain poorly studied. In this work, eight different compositions of GeAsSeSbSnTe chalcogenide glasses were investigated using terahertz time-domain spectroscopy. A number of compositions, in particular GeSeTe and AsSeSbSn, were studied in the terahertz spectral range for the first time. Spectra of the refractive index and extinction coefficient were obtained for studied materials in the spectral range of 0.1-2.2 THz. The experimental frequency dependence of the product of the terahertz power absorption coefficient and the refractive index for the entire set of studied glasses is approximated by a power function. It was established that the exponent of the approximating power functions varies from 1.68 to 2.34 depending on the composition of the chalcogenide glass. For the studied glasses, a correlation was found between the values of the average coordination number characterizing the chalcogenide glass structure, and the values of the exponent of the functions approximating the THz absorption spectra.