Halide Site Engineering of Organic-Inorganic Hybrid Perovskites: A Facile Strategy for Frequency-Controllable...

High-performance electromagnetic wave absorption materials are desperately needed due to the growing serious electromagnetic interference and pollution issues brought on by the quick growth of modern electronic technology and wireless communication. This work uses the organic-inorganic hybrid perovskite MAPbBr_xI_3-x as a model system to address the problem of restricted loss mechanisms and the challenges in changing the absorption bandwidth of single-component wave-absorbing materials. It achieves systematic tuning of electromagnetic wave absorption performance, especially within the effective working frequency spectrum, through accurate halogen site engineering. According to the study, MAPbI₃ (MPI), MAPbBr_1.5I_1.5 (MPIB), and MAPbBr₃ (MPB), which were synthesized using the anti-solvent approach, all demonstrated exceptional microwave absorption capability, with maximum reflection loss values exceeding -37 dB, among which MPB achieves a remarkable value of -42.41 dB at 16.60 GHz. More significantly, this work shows a distinct structure-property relationship between the effective absorption peak frequency range of this series of materials and their band structure: the strongest absorption peak shows a regular blue shift as the material bandgap widens and the bromine content rises. This finding suggests that focused tailoring of the operating frequency band in wave-absorbing materials can be achieved by manipulating the band structure of perovskites by varying the halogen concentration. In addition to confirming the significant application potential of organic-inorganic hybrid perovskites in the field of microwave absorption, this study offers a novel research perspective and material template for precisely and programmably controlling the absorption frequency band of wave-absorbing materials based on their basic electronic structures.