Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Hybridization of Atomic Orbitals I03:24

Hybridization of Atomic Orbitals I

The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
Exceptions to the Octet Rule02:55

Exceptions to the Octet Rule

Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
VSEPR Theory and the Basic Shapes02:52

VSEPR Theory and the Basic Shapes

Overview of VSEPR Theory
π Molecular Orbitals of 1,3-Butadiene01:24

π Molecular Orbitals of 1,3-Butadiene

Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
VSEPR Theory and the Effect of Lone Pairs04:01

VSEPR Theory and the Effect of Lone Pairs

Effect of Lone Pairs of Electrons on Molecule Geometry
Lattice Centering and Coordination Number02:33

Lattice Centering and Coordination Number

The structure of a crystalline solid, whether a metal or not, is best described by considering its simplest repeating unit, which is referred to as its unit cell. The unit cell consists of lattice points that represent the locations of atoms or ions. The entire structure then consists of this unit cell repeating in three dimensions. The three different types of unit cells present in the cubic lattice are illustrated in Figure 1.
Types of Unit Cells
Imagine taking a large number of identical...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Dynamic Proton Transfer Competition and pH-Dependent ORR Mechanism in γN-Modulated Fe-N-C Single-Atom Catalysts.

Inorganic chemistry·2026
Same author

A saddle-shaped OBO-doped nanographene: facile synthesis, adaptive double-layer assembly, and enhanced Lewis acidity.

Chemical science·2026
Same author

Observation of Structurally Diverse Complexes OCeNi(CO)<sub>3</sub><sup>-</sup> and CeNi(CO)<sub>3</sub><sup>-</sup> with the Shortest Ce-Ni Bond and Ce≡O Triple Bond.

The journal of physical chemistry letters·2026
Same author

Highly Selective Purification of Trace <sup>131</sup>I in Radioactive Wastewater via Adaptive Inflatable Organic Cages with Fully Accessible Sites.

Inorganic chemistry·2026
Same author

TGMin-MLP: a new package for predicting the structures of the mono- and poly-nuclear clusters by the machine learning method.

Journal of molecular modeling·2026
Same author

Correction to "Theoretical Insights into the Separation of Nd(III)/Dy(III) by Amine-Terminated Phenanthroline Diimides Ligands".

Inorganic chemistry·2026
Same journal

Enhanced and selective oxygen reduction by iron porphyrin with a biguanide residue in the second coordination sphere.

Chemical science·2026
Same journal

Excited-state orbital angular momentum enables all-optical molecular spin coherence.

Chemical science·2026
Same journal

Polyvinyl-based hole-transporting materials processed with non-destructive and green solvents for tin-lead perovskite solar cells and all-perovskite tandems.

Chemical science·2026
Same journal

Pd-catalyzed regio- and enantioselective allylation of cyclic allylboronates.

Chemical science·2026
Same journal

Covalent polyoxometalate-polyimide hybridization: multi-scale molecular engineering toward high-performance sodium-ion battery anodes.

Chemical science·2026
Same journal

Catalytic visible light-driven alkane dehydrogenation by a di-uranyl germanotungstate.

Chemical science·2026
See all related articles

Related Experiment Video

Updated: May 31, 2026

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

Boron buckminsterfullerene.

Hyun Wook Choi1, Yang-Yang Zhang2, Deniz Kahraman1

  • 1Department of Chemistry, Brown University Providence Rhode Island 02912 USA lai-sheng_wang@brown.edu.

Chemical Science
|May 29, 2026
PubMed
Summary
This summary is machine-generated.

Scientists discovered the first boron fullerene, an 80-atom structure (B80) mimicking carbon buckyballs. This breakthrough opens new avenues for boron-based nanomaterials and chemistry.

More Related Videos

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics
13:58

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics

Published on: September 28, 2016

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Related Experiment Videos

Last Updated: May 31, 2026

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
08:44

Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene

Published on: August 22, 2017

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics
13:58

Probing C84-embedded Si Substrate Using Scanning Probe Microscopy and Molecular Dynamics

Published on: September 28, 2016

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Area of Science:

  • Nanoscience
  • Materials Science
  • Computational Chemistry

Background:

  • Fullerenes, carbon-based nanoscale spheres, are fundamental to nanoscience.
  • Creating similar cage structures with other elements has been challenging due to unique carbon bonding.
  • The quest for non-carbon fullerenes has been a significant research pursuit.

Purpose of the Study:

  • To report the observation of an 80-atom boron fullerene (B80).
  • To characterize the electronic structure and symmetry of the B80 cluster.
  • To compare the properties of boron fullerenes with carbon fullerenes like C60.

Main Methods:

  • Photoelectron spectroscopy was used to study the B80 anion (B80-).
  • Experimental spectral data was compared with simulated spectra of various B80 structures.
  • Density functional theory calculations were employed to analyze electronic structure and bonding.

Main Results:

  • A high-symmetry B80 cluster with a significant energy gap was observed.
  • The experimental photoelectron spectrum matched the simulated spectrum of a B80 buckyball structure.
  • The electronic structure and bonding of B80 were found to closely resemble those of C60.

Conclusions:

  • The discovery of the B80 boron buckyball represents a significant advancement in fullerene research.
  • This finding validates theoretical predictions and experimental observations of boron cage structures.
  • The B80 fullerene is expected to drive further research in boron-based materials and chemistry.