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Published on: July 25, 2025
Solid-State Electron Transfer: Mechanistic Elucidation of Mechanochemical Benzophenone Reduction
1CSGI - Consorzio per lo Sviluppo dei sistemi a Grande Interfase, Via della Lastruccia 3, 50019 SESTO FIORENTINO (FI), Italy.
Abstract:
In this article, a paradigmatic electron-transfer mechanism is borrowed from a solution protocol and subjected to qualitative scrutiny under solid-state conditions, in an effort to determine what truly occurs in the absence of a solvent. The findings discussed here strongly support the hypothesis that an electron transfer mechanism is preserved in the solid-state, although control experiments involving radical scavenging and LAG conditions reveal a sensible shift in the way the same mechanism operates.
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