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Achieving Near-Zero TCF and High Quality Factor in Li2TiO3-Based Dual-Phase Ceramics via Synergistic Phase and
Wei Yang1,2, Huanhuan Guo1,2,3, Jiajia Ren1,2
1School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, China.
Small Methods
|June 3, 2026
Summary
Researchers developed advanced microwave dielectric ceramics by combining gallium-niobium substitution and LiF treatment. This strategy overcomes the quality factor (Q) and temperature coefficient of resonant frequency (TCF) trade-off for next-generation communication systems.
Area of Science:
- Materials Science
- Ceramics Engineering
- Electromagnetics
Background:
- Next-generation communication systems require microwave dielectric ceramics with low dielectric loss and high thermal stability.
- A critical challenge is balancing a high quality factor (Q) with a near-zero temperature coefficient of resonant frequency (TCF).
Purpose of the Study:
- To resolve the trade-off between Q and TCF in microwave dielectric ceramics.
- To develop advanced Li2TiO3 ceramics for enhanced wireless communication applications.
Main Methods:
- Employed a synergistic design integrating (Ga1/2Nb1/2)4+ substitution into Li2TiO3 ceramics.
- Utilized LiF-assisted microstructural engineering and liquid-phase sintering.
- Investigated phase evolution from monoclinic to cubic structures for TCF self-compensation.
Main Results:
- Achieved a dual-phase structure enabling near-zero TCF through self-compensation.
- Reduced dielectric loss via LiF-assisted lower-temperature sintering.
- Optimized Li2Ti0.95(Ga1/2Nb1/2)0.05O3 - 2 wt.% LiF ceramic showed a high Q × f of 129,390 GHz and TCF of +8.5 ppm/°C.
Conclusions:
- The synergistic strategy effectively overcomes the Q-TCF trade-off in microwave dielectric ceramics.
- This approach provides a pathway for developing high-performance ceramics for advanced wireless communication.
- The developed ceramics exhibit promising properties for demanding communication applications.

