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Related Concept Videos

2D NMR: Homonuclear Correlation Spectroscopy (COSY)01:06

2D NMR: Homonuclear Correlation Spectroscopy (COSY)

Homonuclear correlation spectroscopy, or COSY, is a 2-dimensional NMR technique that provides information about coupled protons. Typically, the geminal and vicinal coupling are observed. For example, consider the COSY spectrum of ethyl acetate, where its 1D proton NMR spectrum is plotted along the vertical and horizontal axes with their corresponding chemical shift scale. Three spots on the diagonal corresponding to the three peaks in the 1D proton spectrum are called diagonal peaks. The COSY...
Spectroscopy of Carboxylic Acid Derivatives01:26

Spectroscopy of Carboxylic Acid Derivatives

Infrared spectroscopy is primarily used to determine the types of bonds and functional groups. In carboxylic acid derivatives, a typical carbonyl bond absorption is observed around 1650–1850 cm−1. For esters, the absorption is recorded at around 1740 cm−1, while acid halides show the absorption at about 1800 cm−1. Another acid derivative, the acid anhydrides, exhibit two carbonyl absorption around 1760 cm−1 and 1820 cm−1, arising from the symmetrical and unsymmetrical carbonyl vibration.
In the...
IR and UV–Vis Spectroscopy of Carboxylic Acids01:28

IR and UV–Vis Spectroscopy of Carboxylic Acids

In IR spectroscopy of carboxylic acids, the C=O bond shows a characteristic band between 1710 and 1760 cm⁻¹, and the O–H bond exhibits a broad band between 2500 and 3300 cm⁻¹.
However, the stretching absorptions for the C=O bond vary depending on the structure of carboxylic acids. The C=O bond of the free carboxylic acids shows a higher stretching frequency, 1760 cm−1, while H-bonded carboxylic acids (dimers) exhibit stretching absorptions at a lower frequency, 1710 cm−1. The C=O bond of the...
2D NMR: Overview of Homonuclear Correlation Techniques01:16

2D NMR: Overview of Homonuclear Correlation Techniques

Homonuclear correlation spectroscopy (COSY) is a powerful technique used in Nuclear Magnetic Resonance (NMR) spectroscopy to study the correlations between nuclei of the same type within a molecule. It provides information about scalar couplings between adjacent nuclei, which helps determine connectivity and structural information. There are several COSY variants, each with its unique strengths and experimental parameters.
COSY90 is the standard two-dimensional (2D) COSY experiment that...
UV–Vis Spectroscopy of Conjugated Systems01:32

UV–Vis Spectroscopy of Conjugated Systems

Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent of conjugation in the...
Organic Compounds03:02

Organic Compounds

All living things are formed mostly of carbon compounds called organic compounds. The category of organic compounds includes both natural and synthetic compounds that contain carbon. Although a single, precise definition has yet to be identified by the chemistry community, most agree that a defining trait of organic molecules is the presence of carbon as the principal element, bonded to hydrogen and other carbon atoms. However, some carbon-containing compounds such as carbonates, cyanides, and...

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Updated: Jun 9, 2026

Chromatographic Fingerprinting by Template Matching for Data Collected by Comprehensive Two-Dimensional Gas Chromatography
10:14

Chromatographic Fingerprinting by Template Matching for Data Collected by Comprehensive Two-Dimensional Gas Chromatography

Published on: September 2, 2020

Image-Based Volatile Organic Compound Identification Using the Cosine Similarity Method.

Jingqin Mao1, Zhenxun Wu2, Seán McLoone1

  • 1School of Electronics, Electrical Engineering and Computer Science, Queen's University Belfast, Belfast BT7 1NN, U.K.

ACS Omega
|June 8, 2026
PubMed
Summary
This summary is machine-generated.

This study introduces a novel method for identifying volatile organic compounds (VOCs) using plasma images captured by a phone camera. The technique achieves nearly 100% accuracy in VOC identification, paving the way for low-cost sensors.

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Chromatographic Fingerprinting by Template Matching for Data Collected by Comprehensive Two-Dimensional Gas Chromatography
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Multimodal Nonlinear Hyperspectral Chemical Imaging Using Line-Scanning Vibrational Sum-Frequency Generation Microscopy
08:49

Multimodal Nonlinear Hyperspectral Chemical Imaging Using Line-Scanning Vibrational Sum-Frequency Generation Microscopy

Published on: December 1, 2023

Area of Science:

  • Analytical Chemistry
  • Environmental Science
  • Sensor Technology

Background:

  • Accurate detection and identification of volatile organic compounds (VOCs) are crucial for environmental monitoring, industrial safety, and human health.
  • Current microsensor techniques for VOC detection primarily use electrical or frequency signals, limiting chemical identification capabilities.

Purpose of the Study:

  • To develop a visual and intuitive method for identifying VOCs.
  • To demonstrate the potential of plasma image analysis for VOC identification.

Main Methods:

  • Utilized a helium-based dielectric plasma detector to photoionize gas samples.
  • Recorded plasma color changes upon VOC injection using a standard phone camera.
  • Employed cosine similarity analysis on segmented plasma images for VOC identification.

Main Results:

  • Achieved nearly 100% accuracy in identifying VOCs (n-pentane, benzene, acetone) and their mixtures.
  • Demonstrated the effectiveness of cosine similarity on direct image segmentation for VOC identification.
  • Identified sensitivity to specific image regions impacting identification accuracy.

Conclusions:

  • Plasma image analysis offers a new, accurate approach for VOC identification.
  • The developed method shows potential for creating low-cost, visually intuitive VOC sensors.
  • This technique overcomes limitations of traditional electrical or frequency-based VOC detection methods.