Rice Husk-Derived MCM-41 for Efficient Hg(II) Removal: Performance, Mechanism, and Environmental Safety in Real Water...

Mercury contamination in water poses severe environmental and health risks, requiring efficient and sustainable removal strategies. In this study, rice husk (RH), rice husk-derived materials, including rice ash (RHA), and Mobil Composition of Matter No. 41 (MCM-41) were evaluated as adsorbents for Hg(II) removal in aqueous systems. Among the tested materials, MCM-41 exhibited superior adsorption performance, achieving up to 98% Hg(II) removal under optimal conditions (pH 6.8, 3 g L^-1 of adsorbent, and a pollutant concentration of 0.90 mg L^-1). Adsorption followed a pseudo-second-order kinetic model and was best described by the Langmuir isotherm, indicating monolayer adsorption. The maximum adsorption capacity reached 0.80 mg g^-1. Thermodynamic analysis revealed that the process was spontaneous and exothermic, primarily governed by coordination interactions and hydrogen bonding with surface silanol groups. The adsorbent's applicability was further assessed in distilled water, synthetic industrial wastewater, and river water. Although high removal efficiencies were maintained, a decrease was observed in complex matrices due to competition from coexisting ions. Reusability tests demonstrated that MCM-41 retained its performance over four adsorption cycles. Environmental safety was evaluated through ecotoxicological and microbiological assays. Daphnia magna exhibited high sensitivity to Hg(II) (EC₅₀ values of 0.0220 mg L^-1 at 24 h and 0.0158 mg L^-1 at 48 h), while treated samples showed improved germination indices of Lactuca sativa, particularly in distilled and river water. However, residual toxicity persisted in industrial wastewater matrices. Overall, rice husk-derived MCM-41 is a promising and sustainable adsorbent for Hg(II) removal, though further optimization is needed to mitigate residual toxicity in complex water matrices.