Specific Oil Detection by Canines: Discrimination of Fresh Spill Hydrocarbons from Weathered Background Oil in...

Oil Detection Canines (ODCs) have been proven to detect spilled oil in various environments, including targets and residual oil sequestered along shorelines. A limitation within the capability is that an ODC detects and responds to all types of stranded hydrocarbons, including any from historical spills or naturally occurring chronic oils, such as tarballs washed up from offshore seeps. In locations historically known for chronic tar deposits, the value of a K9-supported Shoreline Cleanup Assessment Technique (SCAT) survey is limited when large numbers of tar deposits are present, because the canine detects and responds to all of them. This thoroughness can slow down SCAT surveys, reduce efficiency by requiring investigation of each response, and fatigue the canines from the number of alerts. A project supported by the Texas General Land Office (TGLO) was designed to investigate the ability of a trained ODC to discriminate hydrocarbons on a beach that represent a newly spilled oil while ignoring other potential "background" oils. In 2021, Texas Tech University's Canine Olfaction Lab conducted a laboratory-based study to investigate canines' ability to respond to weathered oil samples. This research demonstrated that trained canines could effectively discriminate between weathered oils in a laboratory environment. This knowledge was used to design a field program to conduct monthly surveys with two teams: one involved deploying two canines trained on a sample representative of relatively unweathered spilled oils, handled by citizen-scientist volunteers, and the other involved an ODC trained on a range of oil types. The field survey results show that a Specific Oil Detection Canine (SODC) can discriminate between unweathered oil deposits and other background deposits typical of chronic oiling at the same location. Field surveys indicated that SODCs consistently responded exclusively to target oil samples and disregarded naturally occurring background hydrocarbons, while a generalist ODC responded to all hydrocarbon sources present.