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Updated: Jun 14, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
A Pore or not a Pore? Understanding Pore Size Distributions of Non-Graphitic Carbon and Atomically-Dispersed M-N-C
Simon W J Dietzmann1,2, Asad Mehmood1, Jian Liang Low1,3
1Division For Electrochemical Energy Materials, Bundesanstalt für Materialforschung und -prüfung (BAM), Berlin, Germany.
Abstract:
Pore size analysis is essential for understanding and optimizing structure-performance relations of functional carbon-based materials including activated carbons, supercapacitor electrodes and atomically dispersed metal-nitrogen-doped carbon (M-N-C) catalysts. Pore size distribution (PSD) plots based on gas sorption porosimetry often show narrow micropores that are related to the adsorptive properties of named materials, which must be considered as artefacts arising from approximations in classical density functional theory (cDFT) models. By selectively preparing specific in-plane functionalities using pyrolytic template-ion (salt templating) reactions, we herein show that those apparent pores can be explained by preferential adsorption of the adsorbate molecules to specific in-plane functionalities. Tetrapyrrolic Zn-N4 sites are present in ZIF-8 derived carbons, which are converted by Zn-extraction into nitrogen-doped carbons (NDC) comprising tetrapyrrolic H2N4 sites. DFT-based calculation of adsorption energies allows the conclusive assignment of corresponding adsorption phenomena in comparative N2 vs. CO2 vs. Ar adsorption measurements additionally using Langmuir analysis. While the assignment of artefacts may improve the discussion of porosity, the determination of specific adsorption sites may be utilized as a valuable tool in materials science. Advanced models for the important material classes may allow accelerated progress in important energy-related research fields.
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