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Electron-Phonon Origins of Unconventional Resistivity in Moderately Correlated Perovskite Oxides
Jennifer Coulter1, Fabian B Kugler1,2, Harrison LaBollita1
1Flatiron Institute, Center for Computational Quantum Physics, 162 5th Avenue, New York, New York 10010, USA.
Abstract:
Transition-metal perovskite oxides exhibit moderately correlated metallic phases, several of which exhibit a T^{2} resistivity scaling up to temperatures far exceeding the regime where Fermi-liquid electron-electron scattering is expected to dominate. Some of these materials, such as SrMoO_{3}, also exhibit unexplained ultralow room-temperature resistivity. We demonstrate that in SrMoO_{3}, SrWO_{3}, SrTaO_{3}, SrNbO_{3}, and SrVO_{3} electron-phonon scattering results in quadratic-scaling resistivity due to the shape of the Fermi surface and the thermal activation of optical phonons. We also reveal that the origin of the low resistivity of SrMoO_{3} is an overall low electron-phonon coupling strength, and identify SrWO_{3} and SrTaO_{3} as other possible low-resistivity oxides. Additionally, we find that the strength of electron-phonon coupling is sensitive to structural distortions, energies of optical phonons, and the treatment of electronic correlations. This suggests design principles for finding other ultrahigh conductivity transition-metal oxides, and has significant implications for theoretical interpretation of direct-current resistivity in transition-metal oxides and beyond.
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