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Updated: Jun 20, 2026

09:17
Assembly of Gold Nanorods into Chiral Plasmonic Metamolecules Using DNA Origami Templates
Published on: March 5, 2019
Chiroptical modulation of gold nanorods by self-assembly: end-to-end vs. side-by-side
Xi Mao1, Abrahan Martinez2, Samantha Williams3
1Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut, 06269, USA. jie.he@uconn.edu.
Abstract:
We report polymer-guided assembly of chiral gold nanorods (AuNRs) in end-to-end (EE) and side-by-side (SS) modes, modulating their chiroptical responses. EE assemblies amplify circular dichroism (CD) response due to the interparticle plasmonic coupling along the continuously helical patterns of c-AuNRs along the chain direction, while SS assemblies reduce CD response as a result of racemic twisting.

