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Halide-based Solid Electrolytes For Advanced All-solid-state Batteries: Design, Interfaces, And Electrochemical Performance.

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Halide-based Solid Electrolytes For Advanced All-solid-state Batteries: Design, Interfaces, And Electrochemical Performance.

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Halide-Based Solid Electrolytes for Advanced All-Solid-State Batteries: Design, Interfaces, and Electrochemical

Shivaraju Guddehalli Chandrappa¹, Gerardo Morell², Ram S Katiyar³

¹Department of Physics, University of Puerto Rico, San Juan, Puerto Rico, 00931, USA. shivugc123@gmail.com.

Nano-Micro Letters

|June 22, 2026

View abstract on PubMed

Summary

This summary is machine-generated.

Halide-based solid electrolytes offer promising performance for all-solid-state batteries due to their stability and conductivity. This review explores their structure, synthesis, and strategies to overcome challenges for next-generation batteries.

Keywords:

All-solid-state batteries Halide-based solid electrolytes High-voltage-based batteries Interfacial stability Lithium-ion batteries Post-lithium-ion batteries

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

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Published on: November 11, 2013

Area of Science:

Materials Science
Electrochemistry
Solid-State Batteries

Background:

Halide-based solid electrolytes (HSEs) are emerging as superior alternatives to traditional solid electrolytes in all-solid-state batteries (ASSBs).
HSEs exhibit wide electrochemical windows, good ionic conductivity, and improved air stability, making them attractive for advanced energy storage.

Purpose of the Study:

To review recent advancements in halide-based solid electrolytes for all-solid-state batteries.
To analyze the structure-property relationships influencing ion transport and interfacial stability in HSEs.
To identify research pathways for developing scalable, high-performance HSEs for next-generation ASSBs.

Main Methods:

Categorization of HSEs based on central metal chemistry.

Examination of factors affecting ionic conductivity and stability.

Investigation of synthesis methods (mechanochemical, co-melting, wet-chemical) for phase formation, scalability, and defect control.

Analysis of strategies like bilayer and dual-electrolyte design for interface engineering.

Main Results:

HSEs show potential for high ionic conductivity and electrochemical stability, crucial for ASSBs.
Interfacial instability, conductivity-stability trade-offs, mechanical issues, and cost remain significant challenges.
Synthesis methods impact microstructure and device performance metrics like critical current density and area-specific resistance.

Conclusions:

Despite challenges, HSEs are a promising class of materials for next-generation all-solid-state batteries.
Interface engineering and optimized synthesis are key to unlocking the full potential of HSEs.
Further research is needed to address remaining hurdles for scalable, high-performance applications.