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Related Concept Videos

Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
π Molecular Orbitals of the Allyl Cation and Anion01:18

π Molecular Orbitals of the Allyl Cation and Anion

An allyl group is a three-carbon conjugated system where the sp³-hybridized allylic carbon is bonded to a CH=CH2 group via a single bond. Allyl anions can be obtained by treating propene with a strong base that can deprotonate methyl groups. Allyl cations are formed as intermediates during substitution reactions involving allylic halides. In both cases, the hybridization of the allylic carbon changes from sp3 to sp2, giving rise to a carbon chain with three sp2-hybridized carbons, each with an...
Bonding in Metals02:32

Bonding in Metals

Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.

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Updated: Jun 25, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

Altermagnetic Metal-Organic Frameworks.

Diego López-Alcalá1, Andrei Shumilin1, José J Baldoví1

  • 1Instituto de Ciencia Molecular, Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.

Journal of the American Chemical Society
|June 23, 2026
PubMed
Summary
This summary is machine-generated.

Altermagnetism, a novel magnetic state, shows spin splitting without net magnetization. Metal-organic frameworks (MOFs) offer a tunable platform to engineer this phenomenon for spintronics.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Chemistry

Background:

  • Altermagnetism is a new class of magnetic materials with momentum-dependent spin splitting and zero net magnetization.
  • Its origin is linked to symmetry operations connecting spin sublattices.
  • Current altermagnet candidates are inorganic crystals with fixed symmetries.

Purpose of the Study:

  • To explore metal-organic frameworks (MOFs) as a platform for engineering altermagnetism.
  • To discuss the potential of MOFs in realizing and controlling altermagnetic properties.
  • To highlight challenges and future directions for altermagnetism in framework materials.

Main Methods:

  • Review of altermagnetism in the context of magnetic and electronically active metal-organic networks.
  • Discussion of reticular chemistry's role in controlling MOF properties.
  • Analysis of theoretical proposals and experimental challenges.

Main Results:

  • MOFs offer precise control over lattice geometry, dimensionality, and electronic structure via reticular chemistry.
  • These tunable features position MOFs as promising candidates for realizing altermagnetism.
  • Key challenges include translating theoretical concepts into experimentally accessible systems.

Conclusions:

  • MOFs provide a versatile platform for engineering altermagnetism due to their tunable nature.
  • Further research is needed to overcome challenges in experimental realization and control.
  • Coordination framework materials open new avenues for spintronics research.