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Related Experiment Video

Updated: Jun 27, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

Surface-Functionalized LLZO-Incorporated Multilayer Composite Solid Electrolytes for Dendrite Suppression and

Fazal Ur Rehman1, Minhong Woo1, Hyesoo Choi1

  • 1Department of Polymer Engineering, Chonnam National University, Gwangju, South Korea.

Advanced Materials (Deerfield Beach, Fla.)
|June 26, 2026
PubMed
Summary

Researchers developed a novel composite solid electrolyte for safer, high-energy lithium-metal batteries. This advanced material enhances ionic conductivity and mechanical stability, overcoming key challenges for commercialization.

Keywords:
dendrite suppressionionic transport enhancementlithium metal batterysurface modified LLZOtri‐layered electrolytes

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Published on: March 7, 2018

Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid polymer electrolytes are crucial for safe, high-energy lithium-metal batteries (LMBs).
  • Commercialization of LMBs is hindered by dendritic lithium growth, interfacial instability, and low ionic conductivity.

Purpose of the Study:

  • To develop a multifunctional composite solid electrolyte (CSE) that addresses challenges in LMBs.
  • To improve interfacial properties and mechanical reinforcement for enhanced battery performance and safety.

Main Methods:

  • Fabrication of a tri-layered CSE with PEO/LiTFSI outer layers and a reinforced inner layer.
  • Inner layer reinforcement using polydopamine-coated Li7La3Zr2O12 (PDA@LLZO) and poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) (PPP).
  • Characterization of ionic conductivity, transference number, anodic stability, and cycling performance in Li/LFP full cells and Li/Li symmetric cells.

Main Results:

  • The optimized CSE-30 (30 wt% PDA@LLZO) exhibited significantly enhanced ionic conductivity (5.60×10⁻³ S cm⁻¹ at 60°C) and Li⁺ transference number (0.81).
  • Achieved high anodic stability (5.6 V vs. Li/Li⁺) and suppressed dendritic lithium growth in symmetric cells over 1000 hours.
  • Demonstrated excellent cycling stability in Li/LFP full cells, with 80% capacity retention after 1000 cycles.

Conclusions:

  • The multifunctional CSE design effectively integrates efficient Li⁺ transport and mechanical resilience.
  • This approach overcomes critical limitations of current solid polymer electrolytes for next-generation solid-state LMBs.
  • The developed composite solid electrolyte shows great promise for advancing safe and high-performance lithium-metal batteries.