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Updated: Jul 1, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

Synthesis of Cationic Calcium Amido Complexes via Silylium-Mediated Abstraction Reactions

Lucas Winkler1, Alexander Hinz1,2

  • 1Karlsruhe Institute of Technology (KIT), Institute of Inorganic Chemistry (AOC), Kaiserstr. 12, Karlsruhe 76131, Germany.

Inorganic Chemistry
|June 30, 2026
PubMed

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Amides are synthesized by treating carboxylic acids with amines in the presence of dehydrating agents like dicyclohexylcarbodiimide (DCC).
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Subsequently, the amine acts as a nucleophile that attacks the acylating agent to form a tetrahedral intermediate. In the...
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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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Acid-catalyzed hydrolysis:
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