Review: Trace and Residual Rare-Earth Effects on Inclusion Evolution and Nb-Ti-V Precipitation in Microalloyed Steels

This review focuses on the effects of trace and residual rare-earth elements on inclusion evolution and Nb-Ti-V precipitation behavior in microalloyed steels. Existing studies indicate that trace rare-earth elements can transform conventional Al₂O₃- and MnS-type inclusions into rare-earth oxides, oxysulfides, and sulfides, while also modifying local interfacial states and solute distributions through segregation and interfacial activity. These changes further affect the nucleation sites, growth behavior, coarsening tendency, and spatial distribution of NbC, TiN, VC, and related carbonitrides. To explain the seemingly contradictory precipitation responses reported in the literature, this review examines rare-earth effects from the perspectives of inclusion inheritance, heterogeneous nucleation, interfacial energy modification, local solute redistribution, and thermomechanical processing history. The available evidence suggests that the metallurgical role of trace rare-earth elements cannot be attributed solely to inclusion modification. Instead, their effects arise from the combined influence of inclusion evolution, interfacial activity, local chemical heterogeneity, and precipitation kinetics under specific processing conditions. These insights provide practical guidance for alloy and process design by linking rare-earth addition, inclusion control, and Nb-Ti-V precipitation regulation in microalloyed steels.