Ultrasonic Soldering of AlN/Cu Using SiC-Modified Zn5Al3Ti Active Solder

This study investigates the effect of SiC nanoparticle addition on the microstructure, interfacial reactions, and mechanical properties of Zn5Al3Ti active solder used for ultrasonic soldering of AlN ceramic to copper substrates. Composite solders containing 3 and 6 wt.% SiC nanoparticles were prepared and applied under flux-free ultrasonic soldering conditions. The solder alloys were evaluated by tensile testing, while the soldered joints were evaluated by shear strength testing. The solder microstructure and interfacial regions were characterized using SEM/EDS analysis. The results showed that the addition of SiC nanoparticles modified the microstructure of the Zn5Al3Ti solder and influenced the mechanical performance of the ceramic/metal joints. Among the investigated systems, the AlN/Zn5Al3Ti + 6 wt.% SiC/Cu joint exhibited the highest shear strength, reaching approximately 101 MPa. SEM/EDS observations revealed the formation of compact multilayered interfacial regions, including possible Cu-Zn intermetallic phases at the Cu/solder interface and Al-Ti-Zn-based reaction products near the solder/AlN interface. The improved joint performance may be attributed to the combined effect of SiC-induced microstructural modification, the presence of Si-containing particles, and the formation of compact metallurgical bonds. The results indicate that Zn5Al3Ti solder modified with 6 wt.% SiC nanoparticles is a promising material for producing strong AlN/Cu joints under the applied ultrasonic soldering conditions.