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Valorization of Expanded Polystyrene by Embedding of High GFRP Loading Through Cold-Mixing Solvent-Assisted Process.
Federico Olivieri1, Stefano Scognamiglio1, Roberto Avolio1
1Institute for Polymers, Composites and Biomaterials, National Research Council of Italy, Via Campi Flegrei 34, 80078 Pozzuoli, Italy.
This study developed a solvent-assisted method to recycle glass-fiber-reinforced polymer (GFRP) waste into recycled expanded polystyrene (ePS). Optimal GFRP particle size enhances composite performance, offering a sustainable solution for waste valorization.
Area of Science:
- Materials Science
- Polymer Science
- Waste Management
Background:
- Growing environmental concerns regarding glass-fiber-reinforced polymer (GFRP) waste accumulation.
- Need for scalable and effective recycling strategies for GFRP and recycled expanded polystyrene (ePS).
Purpose of the Study:
- To develop a solvent-assisted cold mixing process for high GFRP content incorporation into ePS.
- To investigate the impact of GFRP particle size distribution on composite properties.
- To evaluate the recyclability and performance retention of the resulting composites.
Main Methods:
- Solvent-assisted cold mixing of GFRP (up to 75 wt%) into ePS.
- Characterization of composite properties, focusing on particle size and filler content effects.
- Assessment of mechanical properties, including impact resistance and performance after reprocessing.
Main Results:
- Intermediate GFRP particle sizes (0.25 mm) yielded optimal dispersion and mechanical properties.
- Fine GFRP fractions led to defects and reduced impact resistance.
- Solvent-assisted method ensured homogeneous dispersion at high filler loadings, enabling melt processing.
- Reprocessed composites maintained significant chemical and mechanical integrity with minor losses.
Conclusions:
- A sustainable method for valorizing both ePS and GFRP waste was demonstrated.
- Highly loaded GFRP/ePS composites with preserved functionality can be produced.
- The process offers improved resource efficiency and addresses environmental challenges of GFRP waste.
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