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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Selective Oxidation From Toluene to Benzaldehyde via 4f-Orbital Involvement

Shuai Qin1, Wenlong Yang1, Jiaolong Meng2

  • 1School of Chemistry and Chemical Engineering, Hainan University, Haikou, China.

Angewandte Chemie (International Ed. in English)
|July 21, 2026
PubMed
Summary

Researchers developed Sm-doped Bi2WO6 nanosheets for selective toluene oxidation. This advanced catalyst achieves high conversion to benzaldehyde using f-orbital catalysis and interfacial synergy.

Keywords:
Sm‐doped Bi2WO6frustrated Lewis pairsf‐Orbital engineeringphotocatalytic oxidation

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