Study on the Process of Intermolecular Forces and Electrostatic Force Between Cations and Nano-SiO₂ Based on...

Although low-permeability oil reservoirs boast abundant resources, oil recovery remains relatively low due to the limitations of current water flooding development technology in oilfields. To address the current challenges of low-permeability oil reservoirs, nano-SiO₂ particle aqueous solutions, instead of conventional water injection, have been applied to these reservoirs, which can achieve promising results. Nevertheless, due to the simple surface structure of nano-SiO₂ particles, the unsaturated hydroxyl groups on their surfaces tend to undergo electrostatic attraction with cations in formation water, leading to particle aggregation and flocculation, ultimately compromising their stability. Therefore, studying the interaction between nano-SiO₂ particles and cations in saline solutions is of great significance for providing guidance on the application of nano-SiO₂ particles in low-permeability oilfields. In light of this, this paper employs molecular dynamics simulations and quantum chemical methods to investigate the processes of interactions between nano-SiO₂ particles and cations from a microscopic perspective. The results indicate that the interaction zone between monovalent cations and nanoparticles lies approximately 0.2 nm to 0.3 nm away from the particle surface. In comparison, the interaction zone between divalent cations and nanoparticles extends roughly from 0.3 nm to 0.4 nm from the particle surface. The range and depth of influence of divalent cations are more pronounced. No covalent or ionic bonds are formed between monovalent cations and nanoparticles. However, divalent cations can form ionic bonds with nanoparticles, thereby altering their structural configuration. Among these interactions, electrostatic forces represent the dominant interaction force responsible for changing the configuration of nano-SiO₂ particles, whereas van der Waals forces and hydrogen bonding forces are merely weak interactions. Moreover, as the valence state of the cation increases from monovalent to divalent, the cation forms new ionic bonds with the nano-SiO₂ particles, significantly modifying their structural configuration and further undermining their stability. The findings of this study can improve our understanding of the existing state of nano-SiO₂ particles in formation water, which can help to improve the application effect of nano-SiO₂ particles in low-permeability oil fields.