Design of Cu₂O_(O)@Cu₂O_(P)@AuPt Multilevel Core-Shell Heterostructures via Mild Reduction Strategy with a Dual...

The degradation of organic pollutants through photocatalysis is currently a major research focus. Core-shell heterostructures of metal semiconductors have been widely recognized as an effective strategy for enhancing photocatalytic performance, particularly when alloy nanoparticles are incorporated due to their unique electronic and catalytic properties. However, conventional synthetic approaches typically rely on high-temperature and high-pressure conditions, which often induce undesirable particle overgrowth and aggregation. Herein, AuPt bimetallic alloy nanoparticles were successfully fabricated via two successive in situ redox processes under room-temperature and ambient-pressure conditions, which were in situ integrated with Cu₂O to form multilevel core-shell composite particles. Structurally, an octahedral Cu₂O crystal serves as the inner core (denoted as Cu₂O_(O)), sequentially coated with a Cu₂O nanoparticle (denoted as Cu₂O_(P)) interlayer and a AuPt alloy nanoparticle shell. Functionally, the enhanced photocatalytic activity of Cu₂O_(O)@Cu₂O_(P)@AuPt was proven to be attributed to a dual function of AuPt, which includes an adsorption-induced polarized interface and an efficient charge-transfer mediator with the ohmic contact. This work demonstrates a mild and versatile synthetic strategy for constructing semiconductor-alloy heterostructures, offering valuable insights into the rational design of highly efficient and stable photocatalysts.