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Updated: Aug 5, 2026

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Oxygen heteroatom-induced localized dipole polarization enabling charge separation for efficient photocatalytic H2O2
Li-Cong Wang1, Qia-Chun Lin1, Kai Wen1
1School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, P. R. China. wmliao@gdut.edu.cn.
Abstract:
Sulfur-containing PTZ-COF and oxygen-substituted PXZ-COF were synthesized for photocatalytic H2O2 production. PXZ-COF demonstrated superior catalytic performance, attributed to a unique dipole polarization enhancement mechanism arising from high electronegativity of the oxygen heteroatom combined with an optimal π-conjugated system. This work presents a novel microenvironment engineering strategy for advanced COF photocatalysts.
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