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Updated: Aug 5, 2026

Synthesis and Characterization of Supramolecular Colloids
Published on: April 22, 2016
Activity enhances transport while competing interactions preserve structure in colloidal microphase formers
Horacio Serna1, José Martín-Roca2, Ariel G Meyra3
1Instituto de Química Física Blas Cabrera, Consejo Superior de Investigaciones Científicas (CSIC), Calle Serrano 119, 28006 Madrid, Spain.
Abstract:
Colloidal models with short-range attraction and long range repulsion (SALR) have been extensively studied using theoretical and simulations methods due to their rich and universal equilibrium phase behavior. Using Brownian dynamics simulations, we study the dynamical phase behavior of active suspensions in which colloidal particles interact with each other via a SALR potential. Upon increasing the self-propulsion force of the particles, we observed that the structural transitions the active suspension undergoes resemble those observed in its passive counterpart by increasing the temperature of the thermal bath. However, when looking at the transport properties of active and passive suspensions with similar structure, we observed a clear mismatch. We demonstrated that increasing the activity enhances the particles mobility within the SALR fluid while simultaneously preserving the structure. This leads to a structure-dynamics decoupling induced by the activity while highlighting the structural memory of SALR potentials under non-equilibrium conditions.
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