Microwave-Assisted Desilication as a Route to Hierarchical Y Zeolites: Linking Pore Architecture, Acidity, and...

Hierarchical zeolites have emerged as an effective strategy to mitigate diffusional limitations and catalyst deactivation during the catalytic cracking of heavy feedstocks. However, conventional alkaline desilication often lacks selectivity, leading to partial loss of crystallinity and unfavorable alterations in acidic properties. In this work, microwave-assisted desilication is explored as an alternative route to engineer hierarchical Y zeolites with improved structural control and catalytic performance. A systematic comparison between conventional and microwave-assisted treatments was carried out using a 0.20 mol L^-1 NaOH solution, followed by hydrothermal stabilization. The resulting materials were comprehensively characterized by X-ray diffraction, nitrogen physisorption, scanning electron microscopy, ICP-OES, and pyridine-adsorbed FTIR. Catalytic performance was evaluated in the cracking of nitrogen-containing vacuum gas oil under microactivity test conditions representative of FCC operation. Microwave-assisted desilication promotes a more homogeneous development of mesoporosity, yielding higher mesopore volumes and larger pore diameters while preserving a greater fraction of the FAU crystalline structure and Brønsted acidity compared to conventional treatment. These features translate into enhanced catalytic behavior, including higher and more stable conversions, increased gasoline selectivity (up to 63 wt%), and significantly reduced coke yields. In addition, spectroscopic and thermal analyses reveal that coke formed on the microwave-treated zeolite is less condensed and more readily oxidizable, indicating a reduced propensity for irreversible deactivation. Finally, the results demonstrate that the mode of energy input during desilication plays a critical role in dictating the balance between pore architecture and acidity, ultimately governing catalytic performance. Microwave-assisted desilication emerges as an efficient strategy for designing hierarchical Y zeolites with improved accessibility, selectivity, and resistance to deactivation under severe FCC conditions.