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Published on: May 31, 2022
Advances in Polyurethane-Modified Asphalt via the Prepolymer Method: Molecular Design, Modification Mechanisms,
Haoran Sheng1, Rui Ma2, Yiming Li2,3
1Aulin College, Northeast Forestry University, Harbin 150040, China.
Polyurethane (PU) prepolymers enhance asphalt pavement durability by improving compatibility and processing. This review clarifies mechanisms for developing sustainable, long-life road materials.
Area of Science:
- Materials Science
- Civil Engineering
- Polymer Chemistry
Background:
- Asphalt pavements degrade over time, leading to costly maintenance.
- Polyurethane (PU) offers excellent mechanical properties and resistance to ageing.
- Incompatibility between PU and asphalt causes phase separation, limiting its use.
Purpose of the Study:
- To review the use of polyurethane prepolymers for asphalt modification.
- To clarify the relationship between material properties, processing, and pavement performance.
- To identify potential applications and future research directions for PU-modified asphalt.
Main Methods:
- Discussion of PU soft/hard segment structures and asphalt composition.
- Analysis of prepolymer synthesis, curing mechanisms, and microstructural evolution.
- Review of pavement performance, storage stability, and engineering applications.
Main Results:
- The prepolymer method improves PU-asphalt compatibility and processing control.
- Adjusting molecular weight and segment ratios optimizes performance.
- Understanding modification mechanisms is key to material development.
Conclusions:
- Polyurethane prepolymers offer a viable route to enhance asphalt pavement durability and longevity.
- Further research should focus on real-world conditions and multiscale evaluation.
- Optimized prepolymer design and processing can lead to scalable, low-carbon road materials.
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