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Updated: Sep 26, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Valorising CO2 for oxidative carboxylation of olefins
Jingjing Ren1, Franck Launay2, Lorenzo Casimiro1
1Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, Sorbonne Université, Campus Pierre et Marie Curie, 4 Place Jussieu, F-75005, Paris, France. richard.villanneau@sorbonne-universite.fr.
Abstract:
Carbon capture and utilization has become of utmost importance and urgency to reduce CO2 concentration and use captured CO2 to synthesize high-value molecular building blocks. A widely exploited reaction is the oxidative carboxylation of olefins to cyclic carbonates, which allows both CO2 fixation and valuable product formation, under environment-friendly conditions. This paper is a perusal of molecular and material-based catalysts reported for this specific reaction, namely metal-based catalysts, nitrogen-based catalysts, oxides and nanocatalysts, with a particular focus on studies published over the last 10 years. The examples are provided with details of their nature and catalytic mechanisms, together with a critical analysis of their advantages and drawbacks, and the improvements that future research in this field should aim to achieve.
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